Physical Chemistry II - N403014
Title: Fyzikální chemie II
Guaranteed by: Department of Physical Chemistry (403)
Faculty: Faculty of Chemical Engineering
Actual: from 2021
Semester: both
Points: 7
E-Credits: 7
Examination process:
Hours per week, examination: 3/2, C+Ex [HT]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
State of the course: cancelled
Language: Czech
Teaching methods: full-time
Teaching methods: full-time
Level:  
Is provided by: B403004
Additional information: http://www.vscht.cz/fch/cz/vyuka/N403014.html
Note: you can enroll for the course repeatedly
you can enroll for the course in winter and in summer semester
Guarantor: Dohnal Vladimír doc. Ing. CSc.
Cibulka Ivan doc. Ing. CSc.
Class: Předměty pro fyzikální chemii
Interchangeability : N403016, N403040, Z403014
Is incompatible with: N403003, N403032, B403016, B403009
Is interchangeable with: AB403004, B403004
Examination dates   Schedule   
Annotation -
The course deals with selected chapters of physical chemistry on advanced level. Knowledge acquired in the basic course Physical Chemistry I is extended to real-behaving systems. Subjects covered involve state behavior of matter, thermodynamics of fluids, phase and chemical equilibria, properties of electrolyte-containing systems, chemical kinetics, and basic concepts of surface chemistry.
Last update: Dohnal Vladimír (16.08.2013)
Aim of the course -

Students will be able to:

  • explain and describe basic relations governing physico-chemical processes
  • solve real physico-chemical problems encountered in chemical engineering practice

Last update: Dohnal Vladimír (16.08.2013)
Literature -

A: A. Malijevský, et. al: Physical chemistry in brief. Institute of Chemical Technology, Prague, 2005. (www.vscht.cz/fch/en/tools/breviary.html)

A: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373

A: Atkins P.W., de Paula J., Fyzikální chemie, Czech Edition, VŠCHT Praha, 2013, 9788070808306

Last update: KNOBLOCL (17.12.2015)
Teaching methods -

Combination of lectures and seminar meetings.

Last update: Dohnal Vladimír (16.08.2013)
Requirements to the exam -

For participation in the exam each student has to get the credit from the seminar meetings. A student will be granted the credit when he/she gains the average 50 per cent of the maximum available from the written tests (partial tests during the semester or the summary test).

Last update: Dohnal Vladimír (16.08.2013)
Syllabus -

1. Molecular approach to physical chemistry.

2. Equations of state for real fluids, theorem of corresponding states.

3. Energetics of chemical reactions, enthalpy balance.

4. Implications of I. and II. Laws of thermodynamics, temperature and presseure dependences of state functions.

5. Thermodynamics of irreversible processes, heat engines, liquefacation of gases.

6. Thermodynamics of solutions, fugacity, activity.

7. Phase equilibia in real systems.

8. Spontaneous chemical change and Gibbs energy, chemical equilibrium in systems of various types.

9. Theory of electrolytic dissociation, equilibria in electrolyte solutions.

10.Difusion, migration of ions in electric field, conductivity, Kohlrausch law.

11.Reversible galvanic cells, types of electrodes, galvanic cells as power sources.

12.Kinetics of simultaneous reactions, kinetics and chemical equilibrium.

13.Reaction mechanisms; photochemical,radical, and catalyzed reactions.

14.Introduction to surface chemistry.

Last update: Dohnal Vladimír (16.08.2013)
Learning resources -

http://www.vscht.cz/fch/en/tools/index.html

http://www.vscht.cz/fch/cz/pomucky/index.html (in Czech)

Last update: Dohnal Vladimír (16.08.2013)
Entry requirements -

Necessary prerequisites for the enrollment are courses N413003 (Mathematics II) and N403011 (Physical Chemistry I).

Knowledge of mathematics and physics on the advanced level is needed and expected.

Last update: Dohnal Vladimír (16.08.2013)
Registration requirements -

Mathematics II, Physical Chemistry I

Last update: Dohnal Vladimír (16.08.2013)
Teaching methods
Activity Credits Hours
Konzultace s vyučujícími 0.5 13
Účast na přednáškách 1.5 42
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 1.5 42
Příprava na zkoušku a její absolvování 2.5 70
Účast na seminářích 1 28
7 / 7 195 / 196
Coursework assessment
Form Significance
Examination test 25
Continuous assessment of study performance and course -credit tests 25
Oral examination 50