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The course deals with selected chapters of physical chemistry on advanced level. Knowledge acquired in the basic course Physical Chemistry I is extended to real-behaving systems. Subjects covered involve state behavior of matter, thermodynamics of fluids, phase and chemical equilibria, properties of electrolyte-containing systems, chemical kinetics, and basic concepts of surface chemistry.
Last update: Kubová Petra (06.03.2019)
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Students will be able to:
Last update: Kubová Petra (06.03.2019)
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Credit must be earned and an exam must be passed to pass the course. Credit is obtained by writing three interim tests (at seminars in weeks 5, 10 and 14) or a cumulative credit test (during the exam period - login via SIS). If a student achieves an average score of 80 or higher, he/she does not have to take the written part of the exam. The exam consists of a written test (unless waived) and an oral examination. Passing the written part with a score of 50 or higher is a prerequisite for being able to take the oral part of the exam. Last update: Řehák Karel (30.08.2024)
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R: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 R: Malijevský A., Physical Chemistry in Brief, Institute of Chemical-technology, 2005. PDF document will be available by the E-learning portal. Last update: Řehák Karel (14.08.2019)
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Combination of lectures and seminar meetings. Last update: Kubová Petra (06.03.2019)
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For participation in the exam each student has to get the credit from the seminar meetings. A student will be granted the credit when he/she gains the average 50 per cent of the maximum available from the written tests (partial tests during the semester or the summary test). Last update: Kubová Petra (06.03.2019)
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1. Molecular approach to physical chemistry. 2. Equations of state for real fluids, theorem of corresponding states. 3. Energetics of chemical reactions, enthalpy balance. 4. Implications of I. and II. Laws of thermodynamics, temperature and presseure dependences of state functions. 5. Thermodynamics of irreversible processes, heat engines, liquefacation of gases. 6. Thermodynamics of solutions, fugacity, activity. 7. Phase equilibia in real systems. 8. Spontaneous chemical change and Gibbs energy, chemical equilibrium in systems of various types. 9. Theory of electrolytic dissociation, equilibria in electrolyte solutions. 10.Difusion, migration of ions in electric field, conductivity, Kohlrausch law. 11.Reversible galvanic cells, types of electrodes, galvanic cells as power sources. 12.Kinetics of simultaneous reactions, kinetics and chemical equilibrium. 13.Reaction mechanisms; photochemical,radical, and catalyzed reactions. 14.Introduction to surface chemistry. Last update: Kubová Petra (06.03.2019)
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Basic information and learning resources: See E-learning
Other literature and learning applications: https://ufch.vscht.cz/studium/literatura https://ufch.vscht.cz/studium/elektronicke_pomucky Last update: Kubová Petra (06.03.2019)
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Fyzikální chemie I, Matematika A, Matematika B, Fyzika I Last update: Kubová Petra (06.03.2019)
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Fyzikální chemie I, Matematika A, Matematika B Last update: Kubová Petra (06.03.2019)
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