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This course shows the use of carbon sources in the preparation of basic organic products ane intermediates. The course is divided on the base of processes used for the production. This sorting enables the accent on similar production design. All processes possess by the similar structure starting with reaction overview. Reaction overview is followed by explanation of kinetic and thermodynamic aspects, examples of catalysts used for this process and information about technical leading of processes. Each process ends by the most important examples of processes. Examples of processes show the simplified basic technologies of chosen compounds. The basic knowledges are taken from organic, physical and analytical chemistry together with chemical engineering. Poslední úprava: Vyskočilová Eliška (20.02.2018)
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Students will be able:
Poslední úprava: Vyskočilová Eliška (20.02.2018)
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The students have to be active in lectures. Two tests (7th and 14th week of semester) followed by oral examination are obligatory. Poslední úprava: Vyskočilová Eliška (22.02.2018)
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Moulijn J.A., Makkee M., Van Diepen A.: Chemical Process Technology, John Wiley, 2001, 0-471-63062-4 Poslední úprava: Kubová Petra (16.05.2022)
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1. Introduction to the subject. Survey of hydrogenation and dehydrogenation processes 2. Chemical equilibrium and kinetics of hydrogenation and dehydrogenation processes 3. Technical aspects of hydrogenation and dehydrogenation processes 4. Survey of oxidations. Amoxidation 5. Kinetics and mechanism of oxidation, catalytic systems 6. Technical aspects of oxidation. Examples of typical processes 7. Halogenation, mechanism, kinetics and selectivity of chlorination 8. Technical aspects of chlorination, examples of typical processes Fluorization, bromination. Feasible degradation of organic halogencompounds, environmental issues. 10. Sulfonation and sulfation, nitration - survey of reactions, technical aspects 11. Amonolysis and hydrolysis - kinetics, mechanism, examples of processes 12. Esterification, survey of acid-catalysed reactions, examples of processes 13. Alkylation - mechanism, kinetics, technology 14. Reactions catalysed by metal complexes. Hydroformylation, methatesis Poslední úprava: Vyskočilová Eliška (02.03.2018)
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http://scholar.google.cz/ http://onlinelibrary.wiley.com/book/10.1002/14356007 Poslední úprava: Vyskočilová Eliška (22.02.2018)
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| Zátěž studenta | ||||
| Činnost | Kredity | Hodiny | ||
| Konzultace s vyučujícími | 0.5 | 14 | ||
| Účast na přednáškách | 1.5 | 42 | ||
| Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1.5 | 42 | ||
| Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
| 5 / 5 | 140 / 140 | |||